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Encyclopedia Britannica - Main :: STE-SUS |
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SUCCINIC ACID, CZH4(CO2H)2 . Two acids corresponding to this empirical formula
Ethylene succinic acid occurs in amber, in various resins and lignites, in fossilized wood
Compositae
spleen
It crystallizes in prisms or plates which melt at 185 C. and boil at 235 C. with partial conversion into the anhydride. It is readily soluble in water. Aqueous solutions of the acid are decomposed in sunlight by uranium salts, with evolution of carbon dioxide and the formation of propionic acid. Potassium permanganate, in acid solution, oxidizes it to carbon dioxide and water. The sodium salt on distillation with phosphorus trisulphide gives thiophene. The esters of the acid condense readily with aromatic aldehydes and ketones to form 7-disubstituted itaconic acids and y-alkylen pyrotartaric acids (H. Stobbe, Ann., 1899, 308, p. 71). ry-Oxyacids are formed when aldehydes are heated with sodium succinate and sodium acetate. Numerous salts of the acid are known, the basic ferric salt being occasionally used in quantitative analysis for the separation of iron from aluminium.Succinyl chloride, obtained by the action of phosphorus pentachloride on succinic acid, is a colourless liquid which boils at 19o C. In many respects it behaves as though it were dichlorbutyro-lactone, CiH` 0; e.g. on reduction it yields butyro-lactone, and when condensed with benzene in the presence of aluminium chloride it yields chiefly y-diphenylbutyro-lactone. succinic anhydride, C2H4(CO)2O, is obtained by heating the acid or its sodium salt with acetic anhydride; by the action of acetyl chloride on the barium salt; by distilling a mixture of succinic acid and succinyl chloride, or by heating succinyl chloride with anhydrous oxalic acid. It crystallizes in plates which melt at 12o C., and distils without decomposition. It is slowly dissolved by water with the formation of the acid. It combines readily with the meta-aminophenols to form rhodamines, which are valuable dyestuffs. Heated in a current of ammonia it gives succinimide, which is also obtained on heating acid ammonium succinate. It crystallizes in colourless octahedra which melt at 125126 C., and is easily soluble in water. When warmed with baryta water it yields succinamic acid, HO2CCH2CH2CONH2; and with alcoholic ammonia at 10o C. it gives succinamide. The imino hydrogen atom is easily replaced by metals. Distillation with zinc dust gives pyrrol (q.v.). By the action of bromine in alkaline solution it is converted into /-aminopropionic acid. Succinamide, C2H4(CONH2)2, best obtained by the action of ammonia on diethyl succinate, crystallizes in needles which melt at 242243 C., and is soluble in hot water. Succinonitrile, C2H4(CN)2, is obtained by the action of potassium cyanide on ethylene dibromide or by the electrolysis of a solution of potassium cyan-acetate. It is an amorphous solid which melts at 54550 C. On reduction with sodium in alcoholic solution it yields tetraethylene diamine (putrescein) and pyroilidine. Methyl succinic acid (pyrotartaric acid), H02CCH2CH(CH2).0O2H, is formed by the dry distillation of tartaric acid; by heating pyruvic acid with concentrated hydrochloric acid to 18o C.; by the reduction of eitraconic and mesaconic acids with sodium amalgam; and by the hydrolysis of 0-cyanbutyric acid. It crystallizes in small prisms which melt at 112 C. and are soluble in water. It forms an anhydride when heated. The sodium salt on heating with phosphorus trisulphide yields methylthiophen. Ethylidene succinic acid or isosuccinic acid, CH3.CH(CO2H)2, is produced by the hydrolysis of a-cyanpropionic acid and by the action of methyl iodide on sodio-malonic ester. It crystallizes in prisms which melt at 12o C. (T. Salzer, Journ. prak. Chem., 1898 12], 57, p. 497), and dissolve in water. It does not yield an anhydride, but when heated loses carbon dioxide and leaves a residue of propionic acid. It may be distinguished from the isomeric ethylene succinic acid by the fact that its sodium salt does not give a precipitate with ferric chloride. End of Article: SUCCINIC ACID, CZH4(CO2H)2 If you wish, you can link directly to this article.
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