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Encyclopedia Britannica



RELATION OF

This article appears in Volume V05, Page 275 of the Encyclopedia Britannica.

Encyclopedia Britannica - Main :: RAY-RHU
RELATION OF SURFACE-TENSION TO TEMPERATURE
It appears from the experiments of
Brunner
  and of
Wolf
  on the
ascent of water in tubes that at the temperature I centigrade T =752o (1-0.001870 (
Brunner
 ) ;
=76o8 (1ooo2t+0.0000041512), for a tube 02346 cm.
diameter
  (
Wolf
 ) ;
=77.34(1o.00l8it), for a tube 03o98 cm.
diameter
  (Wolf).
Lord
Kelvin
  has applied the principles of Thermodynamics to determine the thermal effects of increasing or diminishing the area of the free surface of a liquid, and has shown that in order to keep the temperature
constant
  while the area of the surface increases by unity, an amount of heat must be supplied
275
to the liquid which is dynamically equivalent to the product of the
absolute
  temperature into the decrement of the surface-tension per degree of temperature. We may
call
  this the latent heat of surf ace-extension.
It appears from the experiments of C. Brunner and C. J. E. Wolf that at
ordinary
  temperatures the latent heat of extension of the surface of water is dynamically equivalent to about half the mechanical
work
  doi1e in producing the surface-extension.


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