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Encyclopedia Britannica



REALGAR

This article appears in Volume V22, Page 941 of the Encyclopedia Britannica.

Encyclopedia Britannica - Main :: RAY-RHU
REALGAR , a
mineral
  species consisting of arsenic mono-sulphide (AsS) and occurring as
monoclinic
  crystals of a
bright
  red colour. There is a perfect cleavage parallel to the plane of symmetry (r in fig.). The lustre is resinous, and the streak has the same colour as the crystals, namely, orange-red to aurora-red. The hardness is I22 and the specific gravity 3'55. On exposure to light the crystals crumble to a yellow powder. The name realgar is of Arabic origin, and was used by the alchemists; the substance was known to Theophrastus under the name EavbaplKrt, and to Pliny as Sandaracha. The
mineral
  usually occurs in association with the yellow arsenic sulphide, orpiment. Good crystals are found with ores of silver and lead in the mineral veins of Felsobanya, near Nagy-Banya, Kapnik-Banya and Nagyag, near
Deva
 , in
Hungary
 ; with
blende
  in the
white
  crystalline dolomite of the Binnenthal in Switzerland; and in a bed of sandy clay at Mercur in Utah. It is deposited by the solfataras near Naples and by the hot springs of the Yellowstone National Park. Realgar has been used as a pigment and in pyrotechny for producing a brilliant
white
  fire; but it is now replaced by the artificially prepared compound.
The other native arsenic sulphide, As2S3, known as orpiment (Lat. auripigmentum, meaning " golden paint " ), occurs as foliated masses of a lemon-yellow colour, the foliation being parallel to a direction of perfect cleavage. It is sectile and soft (H.=12 2), and has a specific gravity 3.4. Distinctly developed crystals are rare; they have usually been considered to be orthorhombic and isomorphous with stibnite (Sb2S3), but it is probable that they are really
monoclinic
 . Orpiment is extensively
mined
  near Julamerk in Asiatic Turkey. (L. J. S.)


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