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Encyclopedia Britannica



QUERCITRON

This article appears in Volume V22, Page 742 of the Encyclopedia Britannica.

Encyclopedia Britannica - Main :: PYR-RAY
QUERCITRON , a yellow dyestuff obtained from the bark of the quercitron oak, Quercus tinctoria, a fine forest tree indigenous in North America. The name is a shortened form of " quercicitron," from Lat. quercus, oak, and " citron," and was invented by Dr Edward Bancroft (1744-1821), who by act of
parliament
  in 1785 was granted
special
  privileges in regard to the importation and use of the substance. The dyestuff is prepared by grinding the bark in mills after it has been freed from its black epidermal layer, and sifting the product to separate the fibrous matter, the fine yellow powder which remains forming the quercitron of commerce. The ruddy-orange decoction of quercitron contains quercitannic acid, whence its use in tanning, and an active dyeing principle, quercitrin, C21H220,2. The latter substance is a glucoside, and in aqueous solution under the influence of
mineral
  acids it yields quercetin, C16H6007, which is precipitated, and the pentoside rhamnose. Quercetin is a crystalline powder of a brilliant citron yellow colour, entirely insoluble in cold and dissolving only sparingly in hot water, but quite soluble in alcohol. Either by itself or in some form of its glucoside quercitrin, quercetin is found in several vegetable substances, among others in cutch, in Persian berries (Rhamnus catlaarticus),
buckwheat
  leaves (Polygonum Fagopyrum), Zante fustic
wood
  (Rhus Cotinus), and in rose petals, &c. Quercitron was first introduced as a yellow dye in 1775, but it is. principally used in the form of flavin, which is the precipitate thrown down from a boiling decoction of quercitron by sulphuric acid. Chemically, quercetin is a member of a fairly extensive class of natural colouring matters derived from 13 phenyl benzo-y-pyrone or flavone, the constitution of which followed on the researches of St von Kostanecki, A. G. Perkin, Herzig, Goldschmidt and others. Among the related colouring matters are: chrysin from poplar buds, apigenin from parsley, luteolin from weld and dyers' broom, fisetin from
young
  fustic and yellow
cedar
 , galangin from galanga root, and myricetin from Myrica Nagi.


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