PYROCATECHIN, or PYROCATECHOL
This article appears in Volume V22, Page 693 of the Encyclopedia Britannica.
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PYROCATECHIN, or PYROCATECHOL , ortho-dioxybenzene, C6H4(OH)2, first prepared in 1839 by H. Reinsch on distilling catechin (the juice of Mimosa catechu ); occurs free in kino and in beechwood tar; its sulphonic acid is present in the urine of the horse and man. It results in the alkaline fusion of many resins, and may be prepared by fusing ortho-phenolsulphonic acid, o-chlorphenol, o-bromphenol, and o-phenoldisulphonic acid with potash, or, better, by heating its methyl ether, guaiacol, C6H4(OH) (OCH3), a constituent of beechwood tar, with hydriodic acid.
Pyrocatechin crystallizes in white See Also: - WHITE
- WHITE, ANDREW DICKSON (1832– )
- GILBERT
See Also: - GILBERT
- GILBERT (KINGSMILL) ISLANDS
- GILBERT (or GYLBERDE), WILLIAM (1544-1603)
- GILBERT, ALFRED (1854– )
- GILBERT, ANN (1821-1904)
- GILBERT, GROVE KARL (1843– )
- GILBERT, J
- GILBERT, JOHN (1810-1889)
- GILBERT, MARIE DOLORES ELIZA ROSANNA [" LOLA MONTEZ "] (1818-1861)
- GILBERT, NICOLAS JOSEPH LAURENT (1751–1780)
- GILBERT, SIR HUMPHREY (c. 1539-1583)
- GILBERT, SIR JOSEPH HENRY (1817-1901)
- GILBERT, SIR WILLIAM SCHWENK (1836– )
_17201793_.html">WHITE, GILBERT See Also: - GILBERT
- GILBERT (KINGSMILL) ISLANDS
- GILBERT (or GYLBERDE), WILLIAM (1544-1603)
- GILBERT, ALFRED (1854– )
- GILBERT, ANN (1821-1904)
- GILBERT, GROVE KARL (1843– )
- GILBERT, J
- GILBERT, JOHN (1810-1889)
- GILBERT, MARIE DOLORES ELIZA ROSANNA [" LOLA MONTEZ "] (1818-1861)
- GILBERT, NICOLAS JOSEPH LAURENT (1751–1780)
- GILBERT, SIR HUMPHREY (c. 1539-1583)
- GILBERT, SIR JOSEPH HENRY (1817-1901)
- GILBERT, SIR WILLIAM SCHWENK (1836– )
(1720–1793) - WHITE, HENRY KIRKE (1785-1806)
- WHITE, HUGH LAWSON (1773-1840)
- WHITE, JOSEPH BLANCO (1775-1841)
- WHITE,
RICHARD GRANT (1822-1885) - WHITE, ROBERT (1645-1704)
- WHITE, SIR GEORGE STUART (1835– )
- WHITE, SIR THOMAS (1492-1567)
- WHITE, SIR WILLIAM ARTHUR (1824--1891)
- WHITE, SIR WILLIAM HENRY (1845– )
- WHITE, THOMAS (1628-1698)
- WHITE, THOMAS (c. 1550-1624)
rhombic prisms, which melt at 104 and boil at 245; it is readily soluble in water, alcohol and ether. Ferric chloride gives a green coloration with the aqueous solution, whilst the alkaline solution rapidly changes to a green and finally to a black colour on exposure to the air. It reduces silver solutions in the cold and alkaline copper on heating .
Guaiacol may be obtained directly from beechwood tar, from pyrocatechin by methylation with potash and potassium methyl sulphate at 18o, or from anisol by nitration, reduction of the ortho-nitroanisol to amino-anisol, which is then diazotized and
boiled with water. It melts at 28 and boils at 25o. It is employed
in medicine as an expectorant. The dimethyl ether or veratrol i phosphate (PbCl)Pb4(PO4)3, sometimes occurring in sufficient is also used in medicine . Many other pyrocatechin derivatives have abundance to be mined as an ore of lead. been suggested for therapeutic application. Guaiacol carbonate
is known as duotal, the phosphate as phosphatol, the phosphite as guaiaco-phosphal; phosphotal is a mixture of the phosphites of creosote phenols. The valerianic ester of guaiacol is known as geosote, the benzoic as benzosol, the salicylic as guaiacolsalol, while the glycerin ether appears as guaiamar.
Pyrocatechin readily condenses to form heterocyclic compounds; cyclic esters are formed by phosphorus trichloride and oxychloride, carbonyl chloride, sulphuryl chloride, &c.; whilst ortho-phenylenediamine, o-aminophenol, and o-aminothiophenol give phenazine, phenoxazine and thiodiphenylamine.
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