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Encyclopedia Britannica



PROPYL ALCOHOLS (C3H7OH)

This article appears in Volume V22, Page 450 of the Encyclopedia Britannica.

Encyclopedia Britannica - Main :: PRE-PYR
PROPYL ALCOHOLS (C3H7OH) . Two compounds of this
formula
  exist as explained in the article
ALCOHOLS
 . Normal propyl alcohol, CH3CH2CH2.OH, was obtained in 1853 by G. C. B. Chancel, by submitting fusel oil to fractional
distillation
 . It may be prepared by any of the methods applicable to primary
alcohols
 . It is an agreeable-smelling liquid; boiling at 97.40 C., and miscible with water in all proportions. It cannot be separated from water by fractional
distillation
 , since it forms a mixture of constant boiling point (see DISTILLATION). Oxidation converts it into propionic acid. It is distinguished from
ethyl
  alcohol by its insolubility in a cold saturated
calcium
  chloride solution.
Iso-propyl alcohol (CH3)2CHOH, was obtained by M. P. E. Berthelot in 1855 by
heating
  the addition compound of propylene and sulphuric acid with water, and in 1862 by C.
Friedel
  by the reduction of
acetone
 . It is a colourless liquid boiling at 82.7 C.


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