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Encyclopedia Britannica



ORPIMENT (auripigmentum)

This article appears in Volume V20, Page 329 of the Encyclopedia Britannica.

Encyclopedia Britannica - Main :: ORC-PAI
ORPIMENT (auripigmentum) , arsenic trisulphide, As2S3, or yellow realgar (q.v.), occurring in small quantities as a
mineral
  crystallizing in the rhombic
system
  and of a brilliant
golden
 -yellow colour in Bohemia, Peru, &c. For industrial purposes an artificial
orpiment
  is manufactured by subliming one
part
  of
sulphur
  with two of arsenic trioxide. The sublimate varies in colour from yellow to red, according to the intimacy of the combination of the ingredients; and by varying the relative quantities used many intermediate tones may be obtained. These artificial preparations are highly poisonous. Formerly, under the name of "
king
 's yellow," a preparation of
orpiment
  was in considerable use as a pigment, but now it has been largely superseded by chrome-yellow. It was also at one
time
  used in dyeing and
calico
 -printing, and for the unhairing of skins, &c.; but safer and equally efficient substitutes have been found.


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