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Encyclopedia Britannica



NH2

This article appears in Volume V08, Page 290 of the Encyclopedia Britannica.

Encyclopedia Britannica - Main :: NEW-NUM
NH2 NH2
_1 L
Diorthodiaminodiphenyl, <><>,isobtained by the reduction of the corresponding nitro
compound
  (obtained by the
action
  of
ethyl
  nitrite at o C. on metadinitrobenzidine hydrochloride). Its tetrazo
compound
  on reduction gives a
hydrazine
  which, on warming with hydrochloric
acid
  at 15o C., decomposes into ammonium
N = N
chloride and, phenazone,<><_> (C12H2N2). One of the most important derivatives of
diphenyl
 , from the theoretical point of view, is diphenic
acid
  or diorthodiphenyl carboxylic acid, which can be obtained from diparadiaminodiphenyldiorthocarboxylic acid, H1N >j. NH2, or from phenanthrene (q.v.), the consti-.
HOO COOH
tution of which it determines. See BENZInMNE for diparadiaminodiphenyl.


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