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Encyclopedia Britannica



MESOXALIC ACID (dioxymalonic acid), (HO2C)2C(OH)2

This article appears in Volume V18, Page 187 of the Encyclopedia Britannica.

Encyclopedia Britannica - Main :: MEC-MIC
MESOXALIC ACID (dioxymalonic acid), (HO2C)2C(OH)2 or C3H406, is obtained by
hydrolysis
  of alloxan with baryta
water
  (J. v.
Liebig
 , Ann., 1838, 26, p. 298), by warming caffuric acid with lead acetate
solution
  (E.
Fischer
 , Ann., 1882, 215, p. 283), or, from glycerin diacetate and concentrated nitric acid in the cold (E. Seelig, Ber.,1891,'24,p.3471). It crystallizes in deliquescent prisms and melts with partial decomposition at 119120 C. It behaves as a ketonic acid, being reduced in aqueous
solution
  by
sodium
 
amalgam
  to tartronic acid, and also combining with phenylhydrazine and
hydroxylamine
 . It reduces ammoniacal silver solutions. When heated with
urea
  to too ,C. it forms
allantoin
 . By continued boiling of its aqueous solution it is decomposed into carbon dioxide and glyoxylic acid, C2H404.


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