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Encyclopedia Britannica



HYDRACRYLIC ACID (ethylene lactic acid)

This article appears in Volume V14, Page 34 of the Encyclopedia Britannica.

Encyclopedia Britannica - Main :: HOR-I25
HYDRACRYLIC ACID (ethylene lactic acid) , CH2OHCH2 ('O.2H. an organic oxyacid prepared by acting with
silver
 
oxide
  and
water
  on l3-iodopropionic
acid
 , or from
ethylene
  by the addition of hypochlorous
acid
 , the addition product being then treated with potassium
cyanide
  and hydrolysed by an acid. It may also be prepared by oxidizing the trimethy]ene glycol obtained by the action of hydrobromic acid on allylbromide. It is a syrupy liquid, which on
distillation
  is resolved into
water
  and the unsaturated acrylic acid, CH2: CHCO2H. Chromic and nitric acids oxidize it to oxalic acid and
carbon
  dioxide. Hydracrylic aldehyde, CH2OHCH2CHO, was obtained in 1904 by J. L. Nef (Ann. 335, p. 219) as a colourless oil by
heating
  acrolein with water. Dilute alkalis convert it into crotonaldehyde, CH3CH : CH.CHO.


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