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Encyclopedia Britannica



ETHYLENE, or ETHENE, C2H4

This article appears in Volume V09, Page 851 of the Encyclopedia Britannica.

Encyclopedia Britannica - Main :: EMS-EUD
ETHYLENE, or ETHENE, C2H4 , or H2C:CH2, the first representative of the
series
  of olefine hydrocarbons, is found in coal gas. It is usually prepared by
heating
  a mixture of
ethyl
  alcohol and sulphuric acid. G. S. Newth (Jour. Chen. Soc., 1901, 79, p. 915) obtains a purer product by dropping
ethyl
  alcohol into syrupy phosphoric acid (sp. gr. 1.75) warmed to 200 C., subsequently raising the temperature to 220 C. It can also be obtained by the action of sodium on ethylidene chloride (B. Tollens, Ann., 1866, 137, p. 311); by the reduction of copper acetylide with zinc dust and ammonia; by
heating
  ethyl bromide with an alcoholic solution of
caustic
  potash; by passing a mixture of carbon bisulphide and sulphuretted hydrogen over red-hot copper; and by the
electrolysis
  of a concentrated solution of potassium succinate,
(CH2. CO2K) 2+2H20 = C2H4+2CO2+2KOH +H2.
It is a colourless gas of somewhat sweetish
taste
 ; it is slightly
soluble in water, but more so in alcohol and ether. It can be
liquefied at-1.1 C., under a pressure of 42i atmos, It solidifies
at-181 C. and melts at-169 C. (K. Olszewski); it boils at
-105 C. (L. P. Cailletet), or-102 to-103 C. (K. Olszewski).
Its
critical
  temperature is 13 C., and its specific gravity is o9784
(air =1). The specific gravity of liquid ethylene is o386 (3 C.).
Ethylene burns with a
bright
  luminous flame, and forms a very
explosive mixture with oxygen. For the combustion of ethylene
see FLAME. On strong heating it decomposes, giving, among
other products, carbon, methane and acetylene (M. Berthelot,
Ann., 1866, 139, p. 277). Being an unsaturated hydrocarbon,
it is capable of forming addition products, e.g. it combines with
hydrogen in the presence of
platinum
  black, to form ethane,


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