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Encyclopedia Britannica



DIDYMIUM (from the Gr. &Segos, twin)

This article appears in Volume V08, Page 208 of the Encyclopedia Britannica.

Encyclopedia Britannica - Main :: DEM-DIO
DIDYMIUM (from the Gr. &Segos, twin) , the name given. to the supposed
element
  isolated by C. G. Mosander from cerite (1839-1841). In 1879, however, Lecoq de Boisbaudran showed that Mosander's "
didymium
  " contained samarium; while the residual "
didymium
 ," after removal of samarium, was split by Auer v. Welsbach (Monats. f. Chem'ie, 1885, 6, 477) into two components (known respectively as neodymium and praseodymium) by repeated fractional crystallization of the
double
  nitrate of ammonium and didymium in nitric acid. Neodymium (Nd) forms the
chief
  portion of the old " didymium. " Its salts are reddish
violet
  in colour, and give a characteristic absorption spectrum. It forms oxides of composition Nd203 and Nd205, the latter being obtained by ignition of the nitrate (B. Brauner). The atomic
weight
  of neodymium is 143.6 (B. Brauner, Proc. Chem. Soc., 1897-1898, p. 70). Praseodymium (Pr) forms oxides of composition Pr203, Pr206,xH2O (B. Brauner), and Pr407. The peroxide, Pr407, forms a dark brown powder, and is obtained by ignition of the oxalate or nitrate. The sesquioxide, Pr203, is obtained as a greenish
white
 
mass
  by the reduction of the peroxide. The salts of praseodymium are green in colour, and give a characteristic spark spectrum. The atomic
weight
  of praseodymium is 140'5.


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