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Encyclopedia Britannica



CORROSIVE SUBLIMATE, MERCURIC CHLORIDE

This article appears in Volume V07, Page 197 of the Encyclopedia Britannica.

Encyclopedia Britannica - Main :: COR-CRE
CORROSIVE SUBLIMATE, MERCURIC CHLORIDE , PER-CHLORIDE OF
MERCURY
  (HgC12), a
white
  solid obtained by the action of chlorine on
mercury
  or calomel, by the addition of hydrochloric acid to a hot, strong solution of mercurous nitrate, Hg2(NO3)2+4HC1=2HgC12+2H2O-1-2NO2f and, commercially, by
heating
  a mixture of mercuric sulphate and common
salt
 , the mercuric chloride subliming and being condensed in the form of small rhombic crystals. It melts at 288, and boils at 303; it is sparingly soluble in cold water, more so in hot; it is very soluble in
alcohol
  and ether. It is soluble in hydrochloric acid forming compounds such as HgC12.2HC1, 3HgC12.4HC1, 2HgC12HC1; according to the temperature and concentration; it also forms
double
  salts with many chlorides; sal alembroth, 2NH4C1HgCl2H2O, is the compound with ammonium chloride. It absorbs ammonia to form HgC12NH3, which may be distilled without decomposition. Various oxychlorides are formed by digesting corrosive sublimate with mercuric
oxide
 . Corrosive sublimate has important applications in medicineas an astringent, stimulant,
caustic
  and antiseptic (see MERCURY).


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