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Encyclopedia Britannica



CO2H

This article appears in Volume V25, Page 893 of the Encyclopedia Britannica.

Encyclopedia Britannica - Main :: CLI-COM
CO2H I~H2 HCOH
02H,
while the natural xylose, which produces l-tartaric
acid
  by the substitution of CO2H for CHO.CHOH, corresponds to
chloric, nitric, chloric, acetic, formic, sulphuric, oxalic, phosphoric, perchloric acids the specific rotation (calculated for the
base
 ) only varies from -272 to -288; H. H. Landolt found the same thing for active acids, the mono lithium,
sodium
 , potassium and ammonium tartrates varying only between 27.5 and 28.5 (calculated for the
acid
 ). A corresponding
rule
  may be expected where both
base
  and acid have rotatory
power
 ; the molecular rotation will be the sum of those for base and acid in salts with inactive radicles. Each of these rules finds sufficient explanation in
Arrhenius
 's view of electrolytic dissociation, which admits that diluted electrolytes are split up in their ions, and so the salts of
quinine
  (Q) owe their
rotatory
power
  to the ion QH, those of acid tartrates to the ion


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