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Encyclopedia Britannica



CH2 CH

This article appears in Volume V22, Page 33 of the Encyclopedia Britannica.

Encyclopedia Britannica - Main :: CAU-CHA
CH2 CH = CH CH2 -- CH =CH CH2CH2CH ,a -'des-methyl cyclo-octadiene granatanine
Cyclo-octadiene, CSH12, as above prepared, is a strong-smelling oil which decolorizes potassium permanganate
solution
  instantaneously. It readily polymerizes to a di-cyclo-octadiene and polymer (C8H12~ (R. Willstatter, Ber., 1905, 38, pp. 1975, 1984; G. Ciamician and P. Silber, Ber., 1893, 26, p. 2750; A. Piccinini,
Gaza
 ., 1902, 32, I p. 260). i3-cyclo-octadiene has been prepared from methyl granatinine iodmethylate.
Cyclo-octane, C3H18 is obtained by the reduction of the above unsaturated hydrocarbon by the
Sabatier
  and Senderens's method. It is a liquid which boils at 146.3-148 C. and possesses a strong camphor odour. On oxidation it yields suberic acid (R. Willstatter, Ber., 1907, 40, pp. 957). O. Doebner (Bee., 1902, 35, pp. 2129, 2538; 1903, 36, p. 4318) obtained compounds, which in all
probability
  are cyclo-octadienes, by the
distillation
  of p-vinylacrylic acid, sorbic .acid, and cinnamenyl acrylic acid with anhydrous baryta.
Cyclo-nonane
Group
 .
According to N. Zelinsky (Bee., 1907, 40, p. 780) cyclononanone, C9H16O, a liquid boiling at 95-97 C., is formed on distilling sebacic acid with
lime
 , and from this, by reduction to the corresponding secondary
alcohol
 ,
conversion
  of the latter into the iodide, and subsequent reduction of this with
zinc
 , cyclo-nonane, C,H18, a liquid boiling at 170-172 C. is obtained.


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