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Encyclopedia Britannica



ARGYRODITE

This article appears in Volume V02, Page 488 of the Encyclopedia Britannica.

Encyclopedia Britannica - Main :: APO-ARN
ARGYRODITE , a
mineral
  which is of
interest
  as being that in which the
element
 
germanium
  was discovered by C. Winkler in 1886. It is a silver sulpho-germanate, Ag8GeS6, and crystallizes in the cubic
system
 . The crystals have the form of the
octahedron
  or rhombic
dodecahedron
 , and are frequently twinned. The botryoidal crusts of small indistinct crystals first found in a silver mine at Freiberg in Saxony were originally thought to be monoclinic, but were afterwards proved to be identical with the more distinctly developed crystals recently found in Bolivia. The colour is iron-black with a purplish tinge, and the lustre metallic: There is no cleavage; hardness 21, specific gravity 6.2. It is of
interest
  to
note
  that the Freiberg
mineral
  was
long
  ago imperfectly described by A. Breithaupt under the name Plusinglanz, and that the Bolivian crystals were incorrectly described in 1849 as crystallized brongniardite. The name argyrodite is from the Greek apyupWhrls,
rich
  in silver.
Isomorphous with argyrodite is the corresponding tin compound AgsSnS6, also found in Bolivia as cubic crystals, and known by the name canfieldite. Other Bolivian crystals are intermediate in composition between argyrodite and canfieldite. (L. J. S.)


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