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Encyclopedia Britannica



ALUNITE, or ALUMSTONE

This article appears in Volume V01, Page 773 of the Encyclopedia Britannica.

Encyclopedia Britannica - Main :: ALM-ANC
ALUNITE, or ALUMSTONE , a
mineral
  first observed in the 15th
century
  at Tolfa, near Rome, where it is
mined
  for the manufacture of alum. Extensive deposits are also worked in Tuscany and
Hungary
 , and at Bulladelah in New
South
  Wales. By repeatedly roasting and lixiviating the
mineral
 , alum is obtained in solution, and this is crystallized out by evaporation.
Alunite
  occurs as seams in trachytic and allied volcanic rocks, having been formed by the action of sulphureous vapours on
these rocks. The
white
 , finely granular masses somewhat resemble limestone in
appearance
 , and the more compact kinds from
Hungary
  are so hard and tough that they are used for millstones. Distinct crystals of
alunite
  are rarely met with in cavities in the massive material;
these are rhombohedra with interfacial angles of 9o 50', so that they resemble cubes in
appearance
 . Minute glistening crystals have also been found loose in cavities in altered rhyolite. The hardness is 4 and the specific gravity 2.6. The mineral is a hydrated basic
aluminium
  and potassium sulphate, KAl3(SO4)2(OH)5. It is insoluble in water, but soluble in sulphuric acid. First called aluminilite by J. C. Delametherie in 1797, this name was contracted by F. S. Beudant in 1824 to alunite. (L. J. S.)


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