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Encyclopedia Britannica



ALKALINE EARTHS

This article appears in Volume V01, Page 685 of the Encyclopedia Britannica.

Encyclopedia Britannica - Main :: AJA-ALL
ALKALINE EARTHS . The so-called alkaline earth-metals are the elements
beryllium
 , magnesium,
calcium
 , strontium and barium. By the early chemists, the
term
  earth was used to denote those non-metallic substances which were insoluble in water and were unaffected by strong
heating
 ; and as some of these substances (e.g. lime) were found to be very similar in properties to those of the alkalis, they were called alkaline earths. The alkaline earths were assumed to be elements until 1807, when Sir H. Davy showed that they were oxides of various metals. The metals comprising this group are never found in the uncombined
condition
 , but occur most often in the form of carbonates and sulphates; they form oxides of the type RO, and in the case of
calcium
 , strontium and barium, of the type R02. The oxides of type RO are soluble in water, the solution possessing a strongly alkaline reaction and rapidly absorbing carbon dioxide on exposure; they are basic in
character
  and dissolve readily in acids with the formation of the corresponding salts. As the atomic
weight
  of the
element
  increases, it is found that the solubility of the sulphates in water decreases.
Beryllium
  to a certain extent stands alone in many of its chemical properties, resembling to some extent the metal
aluminium
 . Beryllium and magnesium are permanent in dry air; calcium, strontium and barium, however, oxidize rapidly on exposure. The salts of all the metals of this group usually crystallize well, the chlorides and nitrates dissolve readily in water, whilst the carbonates,
phosphates
  and sulphates a're either very sparingly soluble or are insoluble in water.


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